Two point charges sit on a line and a probe slides between them. The total potential is the plain sum of the two contributions beside it — no angles, no components. At the midpoint of a +5 / -5 nC pair V is exactly zero while the field is 359.5 N/C; flip one sign and it is the field that vanishes instead. V = k·Q / r, with k = 8.9875e9 N·m²/C².