Temperature is a measure of molecular motion, and the Kelvin scale starts where that motion — in the ideal-gas picture — would stop: 0 K = -273.15 °C. Drag the temperature slider and the molecules in the box slow down as the square root of T, while the Charles-law cylinder beside them shrinks linearly towards zero volume at 0 K. Real matter never gets there: the third law forbids reaching 0 K in a finite number of steps, and quantum zero-point motion remains even at the limit, so what you see below 4 K, and below each gas's boiling point, is an ideal-gas extrapolation rather than a real gas.
vrms: root-mean-square speed — not the mean speed, and not the most probable speed · (3/2)kT: translational, per molecule · kT: k = 8.617333262e-5 eV/K (CODATA 2018)